全文获取类型
收费全文 | 1493篇 |
免费 | 77篇 |
国内免费 | 74篇 |
学科分类
工业技术 | 1644篇 |
出版年
2024年 | 3篇 |
2023年 | 46篇 |
2022年 | 43篇 |
2021年 | 51篇 |
2020年 | 49篇 |
2019年 | 45篇 |
2018年 | 46篇 |
2017年 | 48篇 |
2016年 | 35篇 |
2015年 | 38篇 |
2014年 | 85篇 |
2013年 | 72篇 |
2012年 | 78篇 |
2011年 | 114篇 |
2010年 | 79篇 |
2009年 | 93篇 |
2008年 | 82篇 |
2007年 | 107篇 |
2006年 | 87篇 |
2005年 | 74篇 |
2004年 | 72篇 |
2003年 | 58篇 |
2002年 | 57篇 |
2001年 | 42篇 |
2000年 | 39篇 |
1999年 | 17篇 |
1998年 | 19篇 |
1997年 | 11篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 8篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1951年 | 3篇 |
排序方式: 共有1644条查询结果,搜索用时 390 毫秒
1.
《Ceramics International》2015,41(6):7478-7488
Gas sensing characteristics of one-electrode sensors based on the In2O3 ceramics doped by gallium and phosphorus have been discussed. In2O3-based ceramic was prepared by sol–gel technology. Ozone, CO, CH4 and H2 were used as tested gases. The doping concentration effect on the sensor parameters such as magnitude of response, operating temperature, response and recovery times, sensitivity to the air humidity, and selectivity have been analyzed. It was shown that In2O3 doping by Ga and P could be used for the sensor performance optimization. It was assumed that the appearance of the second phase (InPO4 and Ga2O3) and the change of structural parameters, taking place during doping process, were the main factors controlling the change of operating characteristics in In2O3:P and In2O3:Ga-based sensors. 相似文献
2.
Katerina Zaharieva Maya Shopska Ilyana Yordanova Sonia Damyanova 《Ceramics International》2018,44(1):326-332
Magnesium aluminate-based materials were prepared by applying different methods: (i) mechanochemical milling of the initial mixture of magnesium and aluminium nitrate powders (in appropriate stoichiometric amounts) followed by heat treatment at temperatures of 650 °C and 850 °C and (ii) melting of the mixture of nitrate precursors at 240 °C followed by thermal treatment at 650 °C, 750 °C and 850 °C. The effect of synthesis method on the structure and morphology of the obtained solids was studied by using various techniques such as: nitrogen adsorption-desorption isotherms, powder XRD, IR spectroscopy and SEM. It was shown that the mechanochemical milling performed before calcination procedure leads to obtaining of nanocrystalline magnesium aluminate spinel phase at lower temperature of 650 °C in comparison with the method using thermal treatment only (at 750 °C). The obtained nanomaterials exhibit mesoporous structure. 相似文献
3.
A route to synthesize ZSM‐5 crystals with a bimodal micro/mesoscopic pore system has been developed in this study; the successful incorporation of the mesopores within the ZSM‐5 structure was performed using tetrapropylammonium hydroxide (TPAOH)‐impregnated mesoporous materials containing carbon nanotubes in the pores, which were encapsulated in the ZSM‐5 crystals during a solid rearrangement process within the framework. Such mesoporous ZSM‐5 zeolites can be readily obtained as powders, thin films, or monoliths. 相似文献
4.
5.
ZnLiFeO3(ZLF)高温NTC热敏厚膜材料,是以尖晶石结构的ZnLiFeO3导电陶瓷作厚膜浆料的导电相,以Al2O3瓷为基体,用厚膜工艺制成的。实验表明,在氮气中烧结的ZLF厚膜材料,室温方阻103Ω/□级,B值约1000K。在高温500~700℃范围内,方阻降为102Ω/□级,B值仍小于1000K。是一种很有前途的高温热敏材料。 相似文献
6.
Six synthesized magnesium aluminate spinel-based refractory compositions used in steel and cement applications, were prepared using a two stage sintering process at 1760 °C, starting with approximately 1:1 wt% ratio of pure magnesia and alumina with additions of zirconium silicate (0.5, 1.0 and 2.0 wt%) and chromite (2.0, 3.0 and 5.0 wt%). These compositions were investigated for effects on densification, chemical and mineralogical phases formed. 相似文献
7.
添加剂对尖晶石型锰酸锂性质表征的影响 总被引:1,自引:0,他引:1
以LiOH·H_20和MnO_2为原料,分别掺入H_2BO_3、Al_2O_3、SiO_2和P_2O_5等添加剂,用固相分段法制备尖晶石型锰酸锂。结果表明,SiO_2和P_2O_5可以有效地改善LiMn_2O_4的电化学性能,H_3BO_3对锰酸锂的电化学性能影响不大,而Al_2O_3破坏了LiMn_2O_4的电化学性能。面扫描结果显示,Si或P元素各自都均匀地分散于LiMn_2O_4的物相中。从元素电负性和原子半径的角度分析了B、Si、P和Al元素对尖晶石型LiMn_2O_4结构和性能的影响。 相似文献
8.
9.
10.
A. Stein 《Advanced materials (Deerfield Beach, Fla.)》2003,15(10):763-775
This report highlights developments in the fields of microporous and mesoporous materials that were published mostly during the year 2002. Selected examples are provided to illustrate new zeolite structures, porous coordination materials, mesoporous solids with new compositions, controlled morphologies, and increased hydrothermal and thermal stabilities, as well as porous solids with tunable pore openings or other structural features that can be dynamically modified. A number of applications are discussed, including stabilization of reactive guests, separations, electronic materials, and sensors. 相似文献